Champions League Liveblog: PSV-Napoli and Union SG-Inter

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Join us for all the build-up and action as it happens from the Champions League, as Napoli visit PSV Eindhoven and Inter take on Union Saint-Gilloise.

Both games kick off at 20.00 UK time (19.00 GMT) in Week 3 of the tournament’s League format.

The Nerazzurri are hoping to keep a 100 per cent record after wins over Ajax and Slavia Praha, having rediscovered their Serie A form too.

Antonio Conte’s side lost to Manchester City and beat Sporting CP 2-1, but suffered two defeats in their last three Serie A matches.

Union Saint-Gilloise: Scherpen; Mac Allister, Burgess, Leysen; Khalaili, Zorgane, Rasmussen, Van de Perre, Niang; Ait El Hadj, David

Inter: Sommer; Bisseck, De Vrij, Bastoni; Dumfries, Frattesi, Calhanoglu, Zielinski, Carlos Augusto; Lautaro Martinez, Esposito

PSV Eindhoven: Kovar; Flamingo, Schouten, Gasiorowski, Salah-Eddine; Mauro Junior, Veerman; Man, Saibari, Perisic; Til

PSV bench: Olij, Schiks, Obispo, Dest, Pepi, Wanner, Driouech, Bajraktarevic, Bouadu, Nagalo

Napoli: Milinkovic-Savic; Di Lorenzo, Beukema, Buongiorno, Spinazzola; Gilmour; Politano, Anguissa, De Bruyne, McTominay; Lucca

Napoli bench: Meret, Ferrante, Gutierrez, Juan Jesus, Neves, Olivera, Elmas, Vergara, Ambrosino, Lang

Inter: Sommer; Bisseck, De Vrij, Bastoni; Dumfries, Frattesi, Calhanoglu, Zielinski, Carlos Augusto; Lautaro Martinez, Esposito

Napoli: Milinkovic-Savic; Di Lorenzo, Beukema, Buongiorno, Spinazzola; Gilmour; Politano, Anguissa, De Bruyne, McTominay; Lucca

McTominay DOES start!

The big question mark for Napoli is whether Scott McTominay is fit to start.

Sky Sport Italia report Zielinski will start for Inter rather than Sucic, with Pio Esposito and Lautaro Martinez upfront.

Top of the bill tonight in Brussels: Union vs Inter, in the Champions League. 🎡 pic.twitter.com/k1vz7p2S93

— Royale Union Saint-Gilloise (@UnionStGilloise) October 21, 2025